Page 115 - GreenChemistry2023 Emhetgel

Уургийн хоёрдогч бүтцийг нил улаан туяаны спектрометрийн шингээлтийн үр дүнгийн
-1
-1
1700 см - 1600 см дах утгыг хоёрдугаар зэргийн дефференциалаар тооцоолж
Гауссийн түгэлт ашиглан уургийн α-мушгиа, β-шийт, койл, β-эргэлт зэрэг уургийн
f1
Peak Analysis
хоёрдогч бүтцүүдийн эзлэх хувийг тодорхойлдог [11], [12]. Кератин, нимбэгний хүчлийн
Data Set:[Book1]Sheet1!B"f1"
Date:5/4/2023
Data Set:[Book1]Sheet1!B"f1"
холимог биофильмүүд болон кератин уургийн хоёрдогч бүтцийг тооцоолсон үр дүнг
Date:5/4/2023
BaseLine:Line BaseLine:Line
зураг 5 болон хүснэгт 2-т харуулав. Chi^2=6.84015E-05 Adj. R-Square=9.84591E-01 # of Data Points=101
# of Data Points=101
Adj. R-Square=9.92664E-01
Chi^2=4.49985E-05
SS=3.86987E-03 Degrees of Freedom=86 SS=5.88253E-03 Degrees of Freedom=86
3.0×10 -1
(а) (б)
3.0×10 -1
2.0×10 -1
2
Subtracted Data Subtracted Data 1.0×10 -1
෤
෤
2
d Ш()/d 2 d Ш()/d 2
2.0×10 -1
෤
෤
(a.u.)
(a.u.)
1.0×10 -1
Peak Analysis
Peak Analysis f1
Peak Analysis
Data Set:[Book3]Sheet1!B Peak Analysis Date:5/5/2023 0.0
0.0
Data Set:[Book1]Sheet1!B Peak Analysis Date:5/4/2023 Data Set:[Book1]Sheet1!D"f4" Date:5/4/2023
Date:5/4/2023
Data Set:[Book1]Sheet1!B"f1"
BaseLine:Line
BaseLine:Line Peak Analysis Date:5/4/2023 BaseLine:Line
BaseLine:Line
Date:5/4/2023
Data Set:[Book1]Sheet1!B"f1"
Data Set:[Book1]Sheet1!B
# of Data Points=101
Chi^2=8.16307E-06
Adj. R-Square=9.92596E-01
Chi^2=5.83428E-05
Chi^2=4.49985E-05
# of Data Points=101
Adj. R-Square=9.90638E-01
Chi^2=3.66289E-06 1600 Adj. R-Square=9.99248E-01 # of Data Points=101 1600 Adj. R-Square=9.92664E-01 # of Data Points=101
1650
1700
1700
1650
BaseLine:Line
BaseLine:Line
Date:5/4/2023
Data Set:[Book1]Sheet1!B
SS=7.02024E-04
Degrees of Freedom=86
SS=5.01748E-03
Degrees of Freedom=86
SS=3.86987E-03
Baseline X
SS=3.04020E-04 Degrees of Freedom=83 # of Data Points=101 Degrees of Freedom=86
Baseline X
Долгион тоо (см −1 )
Долгион тоо (см −1 )
Chi^2=3.66289E-06
Adj. R-Square=9.99248E-01
Chi^2=6.84015E-05
# of Data Points=101
Adj. R-Square=9.84591E-01
BaseLine:Line
Fitting Results
Fitting Results
SS=3.04020E-04 Degrees of Freedom=83 # of Data Points=101 4.0×10 -1
Degrees of Freedom=86
SS=5.88253E-03
Chi^2=3.66289E-06
Adj. R-Square=9.99248E-01
g
Peak Type
t
Peak Index (в) Area Intg FWHM Max Height Center Grvty Area I n Peak Index (г) Area Intg FWHM Max Height Center Grvty Area IntgP
Peak Type
P
1 SS=3.04020E-04 2.50804 25.01974 0.09635 1621.28603 113.5322 Gaussian 2.3581 24.10146 0.09402 1620.54476 13.51189
Degrees of Freedom=83
Gaussian
3.0×10 -1 -1
3.0×10 -1
2 1.5×10 Gaussian 8.85517 39.53357 0.21107 1651.77307 247.7783 Gaussian 8.97546 39.16437 0.21587 1650.43902 51.42929
3 2.0×10 -1 Gaussian 3.81802 22.03522 0.16372 1676.34633 320.60022 Gaussian 3.06515 21.72036 0.133 1674.84668 17.56327
4 2.0×10 -1 Gaussian 2.2077 12.67447 0.16562 1687.83436 411.9117 2 Gaussian 1.99106 13.73568 0.13762 1686.53018 11.40875
2
5 Gaussian 1.14494 6.08249 0.17986 1694.49077 d 56.17758 Gaussian 1.06227 8.61213 0.12333 1694.3159 6.08679
Subtracted Data
2
2
෤
2.0×10 -1
d Ш()/d -1 -1 (a.u.)
2.0×10 -1
෤ 1.0×10
Subtracted Data Subtracted Data Subtracted Data Subtracted Data Subtracted Data 1.0×10 -1 1.0×10 -1
2.0×10
(a.u.) 2.0×10 -1 Subtracted Data Ш(෤)/d෤
1.0×10 -1 -2
5.0×10
1.0×10 -1
1.0×10 -1
0.0
0.0
0.0 0.0 Peak Analysis
Data Set:[Book1]Sheet1!B Date:5/5/2023
0.0
1650
1600
0.0 BaseLine:Line 1600 1650 1700
1700
0.0 1600 Chi^2=1.01646E-05 1700 Adj. R-Square=9.98092E-01 # of Data Points=101
Долгион тоо (см −1 )
Baseline X
Baseline X
1650
1650
Fitting Results
1600 Долгион тоо (см −1 ) 1700 Fitting Results
Baseline X
Baseline X
Center Grvty
Max Height
FWHM
Peak Index
Area IntgP
1600
Peak Index
Area Intg
Fitting Results 1600 SS=8.74158E-04 1700 Degrees of Freedom=86 Peak Type Area Intg FWHM Max Height Center Grvty Area IntgP
1650
Peak Type
1700
1650
Fitting Results 1 1 Gaussian 2.89375 31.11328 0.09635 1621.28603 18.00961
0.08979
1625.47121
Gaussian
2.50804
25.01974
13.5322
Baseline X
Peak Index Peak Type Area Intg FWHM 1650 Center Grvty Area IntgP Gaussian 7.98008 39.53357 0.21107 1651.77307 49.66506
Baseline X -1 Max Height
Gaussian
40.4129
2 2
1659.00463
8.85517
0.18714
47.7783
1600
1700
3.0×10
Baseline X (д)
Peak Index
1
0.04947
2.88329
3 316.17081
1.32817
Fitting Results Peak Type Area Intg FWHM Max Height Center Grvty Area IntgP Gaussian 3.81802 22.03522 0.16372 1676.34633 20.60022
16.56443
Fitting Results Gaussian
17.94452
1621.91707
Gaussian
25.80938
0.16492
1683.19162
31.2465
4 448.95243
37.14337
Gaussian
40.21317
0.1968
0.09427
1652.03971
4.02065
6.54215
1 2 Peak Index Gaussian Area Intg FWHM Max Height Center Grvty Area IntgP Gaussian 1.66001 12.67447 0.16562 1687.83436 10.33131
1649.4258
1691.26492
0.18433
11.9117
8.52884
Gaussian
2.2077
Peak Type
Peak Index
Peak Type
6.98218
0.43218
11.54017
Gaussian
0.03577
1610.45209
5 515.51263
1676.97109
4.53556
0.13671
3
1.27411
1695.74598
4.0495
2Fitting Results Gaussian Area Intg FWHM Max Height Center Grvty Area IntgP Gaussian 1.14494 6.08249 0.17986 1694.49077 6.17758
21.31996
0.05645
0.65066
Gaussian
1 3 1 Gaussian 6.54215 24.10146 0.09402 1620.54476 16.67837
1649.4258
0.1968
31.2465
37.14337
2.3581
13.51189
Gaussian
1622.6081
Gaussian
2.41702
0.11101
20.55274
Gaussian
0.07533
11.84412
4
0.9441
11.49465
1687.32455
2 Peak Index Gaussian Area Intg FWHM Max Height Center Grvty Area IntgP
Peak Type
4 2
51.42929
8.97546
6.98218
0.43218
Gaussian
1650.43902
0.03577
39.16437
1610.45209
11.54017
0.21587
1666.37107
Gaussian
26.19372
26.78713
0.1394
3.88197
Gaussian
1693.55206
7.86947
0.64635
6.79639
0.09051
Gaussian
0.1968
31.2465
1649.4258
3 1 3 5 Gaussian 6.54215 20.55274 0.11101 1674.84668 37.14337
16.67837
3.06515
17.56327
Gaussian
21.72036
0.133
2.41702
1622.6081
16.2609 2.0×10 -1
5 2 Gaussian 1.00981 11.54017 0.05865 1682.32158 10.96807
Gaussian
6.98218
0.03577
1610.45209
0.43218
Gaussian
1686.53018
1.99106
2
26.19372
26.78713
4 4 Gaussian 3.88197 13.73568 ෤ 2 0.13762 1666.37107 11.40875
0.1394
d Ш()/d
7.95383
0.02491
2.44089
Subtracted Data
1692.12025
෤
Gaussian
0.20881
1622.6081
Gaussian
0.05865
Gaussian
16.2609
0.12333
1694.3159
8.61213
1.00981
1.06227
6.08679
5 6 3 5 Gaussian 2.41702 20.55274 0.11101 1682.32158 16.67837
10.96807
(a.u.)
0.1394
Gaussian
1666.37107
6 4 Gaussian 3.88197 26.19372 0.02491 1692.12025 26.78713
0.20881
2.44089
7.95383
5 Gaussian 1.00981 16.2609 0.05865 1682.32158 10.96807
6 Gaussian 0.20881 7.95383 0.02491 1692.12025 2.44089
1.0×10 -1
0.0
1600 1650 1700
Baseline X
Fitting Results
Peak Index Peak Type Area Intg FWHM Max Height Center Grvty Area IntgP
1
0.0962
23.01642
2.30693
Зураг 5. Кератин болон биофильмийн Амид I пикүүд дээрх уургийн хоёрдогч бүтэц харьцуулсан
1619.83696
Gaussian
15.18793
Gaussian
7.68025
50.56372
35.44804
2
0.20387
1644.76608
зураг; (а) КНХ4 биофильм; (б) КНХ3 биофильм; (в) КНХ2 биофильм; (г) КНХ1 биофильм; (д)
3
0.14726
4.13793
26.46265
1668.37077
Gaussian
27.24251
5.52579
1683.22837
14.95051
0.83933
Gaussian
0.05296
4
Кератин уураг; 5 Gaussian 0.22481 7.79027 0.02737 1692.20889 1.48005

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